Free three-dimensional carborane carbanions-Reference-Cited by-同舟云学术

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Free three-dimensional carborane carbanions

Published:2021 Issue:31 Volume:12 Page:10441-10447
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Jayaweera H. D. A. Chathumal¹²³⁴^ORCID,Rahman Md. Mamdudur¹²³⁴^ORCID,Pellechia Perry J.¹²³⁴,Smith Mark D.¹²³⁴,Peryshkov Dmitry V.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of South Carolina

3. Columbia

4. USA

Abstract

Free three-dimensional carborane carbanions, which are inorganic siblings of deprotonated aryls with the “naked” anionic carbon atom are reported.

Funder

National Science Foundation

Office of the Vice President for Research, University of South Carolina

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02252K

Reference56 articles.

1. Role of Organolithium Aggregates and Mixed Aggregates in Organolithium Mechanisms

2. 200 Years of Lithium and 100 Years of Organolithium Chemistry

3. Alkyl and Aryl Derivatives of the Alkali Metals: Useful Synthetic Reagents as Strong Bases and Potent Nucleophiles. 1. Conversion of Organic Halides to Organoalkali-Metal Compounds

4. Alkyl and Aryl Derivatives of the Alkali Metals: Strong Bases and Reactive Nucleophiles. 2. Wilhelm Schlenk’s Organoalkali-Metal Chemistry. The Metal Displacement and the Transmetalation Reactions. Metalation of Weakly Acidic Hydrocarbons. Superbases

5. Organosodium and Organopotassium Compounds Part I: Properties and Reactions

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