Why do the Togni reagent and some of its derivatives exist in the high-energy hypervalent iodine form? New insight into the origins of their kinetic stability-Reference-Cited by-同舟云学术

Why do the Togni reagent and some of its derivatives exist in the high-energy hypervalent iodine form? New insight into the origins of their kinetic stability

Published:2017 Issue:48 Volume:19 Page:32179-32183
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Koichi Shungo¹²³⁴^ORCID,Leuthold Benjamin⁵⁶⁷⁸,Lüthi Hans P.⁵⁶⁷⁸^ORCID

Affiliation:

1. Department of Systems and Mathematical Science

2. Nanzan University

3. Nagoya

4. Japan

5. Department of Chemistry and Applied Biosciences

6. ETH Zürich

7. CH 8093 Zürich

8. Switzerland

Abstract

A scheme for the prediction of the kinetic and thermodynamic stability of Togni-type reagents is presented. The scheme is evaluated based on computations of the isomerization and transition state energies of an array of more than 600 compounds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP05943D

Reference18 articles.

1. V. V. Zhdankin , Hypervalent Chemistry: Preparation, Structure and Synthetic Applications of Polyvalent Iodine Compounds , Wiley , Chichester , 1st edn, 2014

2. Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents

3. Why does Togni's reagent I exist in the high-energy hypervalent iodine form? Re-evaluation of benziodoxole based hypervalent iodine reagents

4. Breaking Down the Reactivity of λ3-Iodanes: The Impact of Structure and Bonding on Competing Reaction Mechanisms

5. Dividing a complex reaction involving a hypervalent iodine reagent into three limiting mechanisms byab initiomolecular dynamics

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