Monoclinic LaGa1−xMnxGe2O7: a new blue chromophore based on Mn3+ in the trigonal bipyramidal coordination with longer apical bond lengths

Author:

Saraswathy Divya12,Rao P. Prabhakar12,Sameera S.12,James Vineetha12,Raj Athira K. V.12

Affiliation:

1. National Institute for Interdisciplinary Science and Technology (CSIR)

2. India

Abstract

Substitution of Mn3+ into the trigonal bipyramidal site of monoclinic LaGaGe2O7 produces a blue colored material. Mn–O apical bond distances play a key role in the d–d transitions causing the color.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference20 articles.

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2. B. Fromme , d–d Excitations in Transition-Metal Oxides, Springer-Verlag, Berlin, Heidelberg, 2001

3. R. J. D. Tilley , Colour and The Optical Properties of Materials, John Wiley & Sons, Chichester, UK, 2010

4. Color characteristics of pigments in glaze coatings

5. R. M. Christie , Colour Chemistry, Royal Society of Chemistry, Cambridge, 2001

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