New transmetalation reagents for the gold-catalyzed visible light-enabled C(sp or sp2)–C(sp2) cross-coupling with aryldiazonium salts in the absence of a photosensitizer-Reference-Cited by-同舟云学术

New transmetalation reagents for the gold-catalyzed visible light-enabled C(sp or sp2)–C(sp2) cross-coupling with aryldiazonium salts in the absence of a photosensitizer

Published:2018 Issue:98 Volume:54 Page:13802-13804
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Witzel Sina¹²³,Sekine Kohei¹²³,Rudolph Matthias¹²³,Hashmi A. Stephen K.¹²³⁴⁵^ORCID

Affiliation:

1. Organisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg

2. 69120 Heidelberg

3. Germany

4. Chemistry Department, Faculty of Science, King Abdulaziz University

5. Jeddah 21589

Abstract

The scope of photosensitizer-free visible light-driven gold-catalyzed cross-coupling was evaluated by a wide variety of organoboron and organosilicon species using four equivalents of aryldiazonium salts and (4-CF₃-C₆H₄)₃PAuCl in MeOH.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC08227H

Reference33 articles.

1. Photoredox Transformations with Dimeric Gold Complexes

2. A Highly Efficient Gold-Catalyzed Photoredox α-C(sp3)H Alkynylation of Tertiary Aliphatic Amines with Sunlight

3. Gold-Catalyzed Highly Selective Photoredox C(sp2 )−H Difluoroalkylation and Perfluoroalkylation of Hydrazones

4. Intermolecular Photocatalyzed Heck-like Coupling of Unactivated Alkyl Bromides by a Dinuclear Gold Complex

5. Gold-Catalyzed Photoredox C(sp2) Cyclization: Formal Synthesis of (±)-Triptolide

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