Modification of polybutadiene with trifluoromethyl and clickable azide groups in one shot

Author:

Wang Shengfei1,Zhang Sen1,Feng Chun1,Lu Guolin1,Theato Patrick23ORCID,Huang Xiaoyu1ORCID

Affiliation:

1. Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, People's Republic of China

2. Institute for Chemical Technology and Polymer Chemistry, Karlsruhe Institute of Technology (KIT), Engesser Str. 18, D-76131 Karlsruhe, Germany

3. Soft Matter Synthesis Laboratory, Institute for Biological Interfaces III, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany

Abstract

We report copper-catalyzed intermolecular azide-trifluoromethylation of the alkenyls of PB without any chain degradation and crosslinking.

Funder

National Science Fund for Distinguished Young Scholars

National Natural Science Foundation of China

Bureau of International Cooperation, Chinese Academy of Sciences

Youth Innovation Promotion Association of the Chinese Academy of Sciences

Science and Technology Commission of Shanghai Municipality

Shanghai Municipal Education Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference40 articles.

1. L.Valentini and M. A.Lopez-Manchado , in High-Performance Elastomeric Materials Reinforced by Nano-Carbons , ed. L. Valentini and M. and A. Lopez Manchado , Elsevier , 2020 , pp. 1–14

2. Diversified Applications of Chemically Modified 1,2-Polybutadiene

3. Catalytic Hydrocarboxylation and Hydroesterification Reactions of 1,2-Polybutadiene

4. Catalytic hydrosilylation of diene-based polymers. 1. Hydrosilylation of polybutadiene

5. Synthesis of fluorinated polymers by chemical modification

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3