Understanding the fast kinetics and mechanism of sodium storage in antimony using <i>ab initio</i> grand canonical Monte Carlo simulation and <i>operando</i> X-ray scattering-Reference-Cited by-全球学者库

Understanding the fast kinetics and mechanism of sodium storage in antimony using ab initio grand canonical Monte Carlo simulation and operando X-ray scattering

Published:2024 Issue: Volume: Page:
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Li Manni¹²,Qiu Tian³⁴^ORCID,Welborn Samuel S.¹⁴,Foucher Alexandre C.¹,Fu Jintao¹,Lesel Benjamin K.⁵,Wang Zeyu¹⁶^ORCID,Wang Lin¹^ORCID,Stach Eric A.¹⁴^ORCID,Rappe Andrew M.³⁴^ORCID,Detsi Eric¹⁴^ORCID

Affiliation:

1. Department of Materials Science & Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA

2. Automoive Engineering Research Institute, Jiangsu University, Zhenjiang 212013, China

3. Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, USA

4. Vagelos Institute for Energy Science and Technology (VIEST), Philadelphia, Pennsylvania 19104, USA

5. NanoDian, Los Angeles, California 90095, USA

6. School of Materials Science & Engineering, Jiangsu University, Zhenjiang 212013, China

Abstract

Using ai-GCMC simulations, operando WAXS, and kinetics analysis, we found that the high-rate performance of Sb as an alloy anode in Na-ion batteries is due to the presence of an amorphous intermediate phase formed during sodiation and desodiation.

Funder

Vagelos Institute for Energy Science and Technology, University of Pennsylvania

Center for Hybrid, Active, and Responsive Materials, University of Delaware

Basic Energy Sciences

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D3TA06832C

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1. Controllable embedding of sulfur in high surface area nitrogen doped three dimensional reduced graphene oxide by solution drop impregnation method for high performance lithium-sulfur batteries

2. Recent developments in electrode materials for sodium-ion batteries

3. Carbon Nanosheet Frameworks Derived from Peat Moss as High Performance Sodium Ion Battery Anodes

4. Electrochemical Properties of Electrodeposited Sn Anodes for Na-Ion Batteries