Diastereodivergent asymmetric Michael-alkylation reactions using chiralN,N′-dioxide/metal complexes-Reference-Cited by-同舟云学术

Diastereodivergent asymmetric Michael-alkylation reactions using chiralN,N′-dioxide/metal complexes

Published:2018 Issue:3 Volume:9 Page:688-692
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kuang Yulong¹²³⁴⁵^ORCID,Shen Bin¹²³⁴⁵^ORCID,Dai Li¹²³⁴⁵^ORCID,Yao Qian¹²³⁴⁵^ORCID,Liu Xiaohua¹²³⁴⁵^ORCID,Lin Lili¹²³⁴⁵^ORCID,Feng Xiaoming¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Green Chemistry & Technology

2. Ministry of Education

3. College of Chemistry

4. Sichuan University

5. Chengdu 610064

Abstract

A diastereodivergent asymmetric cascade Michael-alkylation by switching the alkylation step of intramolecular trapping of the aza-ortho-xylylene intermediate or direct S_N2 substitution has been developed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC02757E

Reference51 articles.

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2. C. Wolf , Dynamic stereochemistry of chiral compounds: principles and applications , Royal Society of Chemistry , 2008

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4. W. O. Foye , Foye’s Principles of Medicinal Chemistry , Lippincott Williams & Wilkins , 7th edn, 2013

5. Catalytic Strategies for Diastereodivergent Synthesis

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