Kinetic studies on Lewis acidic metal polyesterification catalysts – hydrolytic degradation is a key factor for catalytic performance-Reference-Cited by-同舟云学术

Kinetic studies on Lewis acidic metal polyesterification catalysts – hydrolytic degradation is a key factor for catalytic performance

Published:2022 Issue:7 Volume:12 Page:2056-2060
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Wolzak Lukas A.¹²^ORCID,van Gemert Rogier³,van den Berg Keimpe J.³,Reek Joost N. H.²^ORCID,Tromp Moniek¹⁴^ORCID,Korstanje Ties J.¹^ORCID

Affiliation:

1. Sustainable Materials Characterization, van 't Hoff Institute for Molecular Sciences (HIMS), University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands

2. Bio-inspired, Homogeneous and Supramolecular Catalysis, van ‘t Hoff Institute for Molecular Sciences (HIMS), University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands

3. Akzo Nobel Car Refinishes BV, Rijksstraatweg 31, 2171 AJ Sassenheim, The Netherlands

4. Faculty of Science and Engineering, Materials Chemistry — Zernike Institute for Advanced Materials, University of Groningen Nijenborgh 4, 9747 AG Groningen, The Netherlands

Abstract

Kinetic studies of Lewis acidic metal-catalyzed polyesterification reactions unveiled that titanium-based catalyst are prone to hydrolytic degradation, while n-BuSnOOH proved to be a robust catalyst.

Funder

Ministerie van Economische Zaken en Klimaat

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY02306C

Reference36 articles.

1. From Lab to Market: Current Strategies for the Production of Biobased Polyols

2. New approaches to producing polyols from biomass

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5. Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency

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