Affiliation:
1. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland
Abstract
Ancillary ligands alter the reactivity of U-nitrides with H+, relevant to N2 conversion to NH3. The amides lead to complete ligand loss and NH3 activation, while for siloxides, the nitride is protonated to NH3 leaving the ancillary ligands intact.
Funder
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
École Polytechnique Fédérale de Lausanne
Publisher
Royal Society of Chemistry (RSC)
Cited by
9 articles.
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