On the mechanism of intermolecular nitrogen-atom transfer from a lattice-isolated diruthenium nitride intermediate-Reference-Cited by-同舟云学术

On the mechanism of intermolecular nitrogen-atom transfer from a lattice-isolated diruthenium nitride intermediate

Published:2023 Issue: Volume: Page:
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Cosio Mario N.¹,Alharbi Waad S.²³^ORCID,Sur Aishanee¹,Wang Chen-Hao¹,Najafian Ahmad²,Cundari Thomas R.²,Powers David C.¹^ORCID

Affiliation:

1. Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255, USA

2. Department of Chemistry, Center of Advanced Scientific Computing and Modeling (CASCaM), University of North Texas, 1155 Union Circle, #305070, Denton, Texas 76203-5017, USA

3. Chemistry Department, Science College, University of Jeddah, Jeddah, Kingdom of Saudi Arabia

Abstract

Computational studies indicate nitrogen-atom transfer at lattice-confined diruthenium sites proceeds by an H-atom abstraction, radical rebound mechanism and corroborate available porosity-dependent kinetic isotope effects.

Funder

U.S. Department of Energy

Welch Foundation

Saudi Arabian Cultural Mission

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/FD/D2FD00167E

Reference59 articles.

1. Stabilizing reactive intermediates through site isolation

2. Acceleration and selectivity enhancement of Diels-Alder reactions by special and catalytic methods

3. MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

4. Immobilized Grubbs catalysts on mesoporous silica materials: insight into support characteristics and their impact on catalytic activity and product selectivity

5. Exploiting Confinement Effects to Tune Selectivity in Cyclooctane Metathesis

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis, characterization, and photochemistry of Ru2(II,III) complexes of chalcogen oxides;Polyhedron;2024-03