Study on the chemical reactivity difference of primary hydroxyl groups in iridoid glycosides-Reference-Cited by-同舟云学术

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Study on the chemical reactivity difference of primary hydroxyl groups in iridoid glycosides

Published:2023 Issue:47 Volume:13 Page:33204-33209
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Kong Yuanfang¹^ORCID,Xu Jindan¹²³,Zhu Pengbo¹²³,Wang Shaopei¹²³,Yang Bin¹²³,Zhang Jingyu¹,Dong Chunhong¹²³

Affiliation:

1. Henan University of Chinese Medicine, Zhengzhou 450046, Henan, China

2. Henan Polysaccharide Research Center, Zhengzhou 450046, Henan, China

3. Henan Key Laboratory of Chinese Medicine for Polysaccharides and Drugs Research, Zhengzhou 450046, Henan, China

Abstract

Two methods of computer simulation and experiments were used to explore the difference of primary hydroxyl groups in iridoid glycosides, which indicate that the chemical reactivity of hydroxyl at C10-position is higher than that of the C6′-position.

Funder

Henan Provincial Science and Technology Research Project

Henan University of Chinese Medicine

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/RA/D3RA05674K

Reference23 articles.

1. P.Wuts , Greene's protective groups in organic synthesis , 2007

2. Regioselective silylation of pyranosides using a boronic acid/Lewis base co-catalyst system

3. Efficient acylation and sulfation of carbohydrates using sulfamic acid, a mild, eco-friendly catalyst under organic solvent-free conditions

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