S(vi) Lewis acids: fluorosulfoxonium cations-Reference-Cited by-同舟云学术

S(vi) Lewis acids: fluorosulfoxonium cations

Published:2016 Issue:84 Volume:52 Page:12418-12421
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Tsao Fu An¹²³⁴,Waked Alexander E.¹²³⁴,Cao Levy¹²³⁴,Hofmann Jordan¹²³⁴,Liu Lei⁵⁶⁷⁸⁹,Grimme Stefan⁵⁶⁷⁸⁹,Stephan Douglas W.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Toronto

3. Toronto

4. Canada

5. Mulliken Center for Theoretical Chemistry

6. Institut fuer Physikalische und Theoretische Chemie

7. Universitaet Bonn

8. D-53115 Bonn

9. Germany

Abstract

Avenues to S-based Lewis acids were developed via the oxidation of aryl-sulfoxides with XeF₂, giving difluorodiarylsulfoxides which react via fluoride abstraction to afford Lewis acidic fluorosulfoxonium cations; this acidity is derived from the S–F σ* orbital and has been probed both experimentally and computationally.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC06929K

Reference54 articles.

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3. Frustrated Lewis Pair Chemistry: Development and Perspectives

4. Frustrated Lewis Pairs

5. Frustrated Lewis Pairs: From Concept to Catalysis

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