Synthesis of alkynyl-functionalized linear and star polyethers by aluminium-catalyzed copolymerization of glycidyl 3-butynyl ether with epichlorohydrin and ethylene oxide
Author:
Affiliation:
1. State Key Laboratory of Fine Chemicals
2. Department of Polymer Science and Engineering
3. School of Chemical Engineering
4. Dalian University of Technology
5. Dalian 116012
Abstract
A novel family of alkynyl-functional linear and star polyethers were prepared by the copolymerization of glycidyl 3-butynyl ether, ethylene oxide and epichlorohydrin catalyzed by i-Bu3Al/H3PO4/DBU.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2019/PY/C8PY01829D
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4. Glycidyl Triazolyl Polymers: Poly(ethylene glycol) Derivatives Functionalized by Azide-Alkyne Cycloaddition Reaction
5. Epicyanohydrin: Polymerization by Monomer Activation Gives Access to Nitrile-, Amino-, and Carboxyl-Functional Poly(ethylene glycol)
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