Asymmetric [3 + 2] cycloaddition of donor–acceptor aziridines with aldehydes via carbon–carbon bond cleavage-Reference-Cited by-同舟云学术

Asymmetric [3 + 2] cycloaddition of donor–acceptor aziridines with aldehydes via carbon–carbon bond cleavage

Published:2016 Issue:6 Volume:7 Page:3775-3779
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Liao Yuting¹²³⁴⁵,Liu Xiaohua¹²³⁴⁵,Zhang Yu¹²³⁴⁵,Xu Yali¹²³⁴⁵,Xia Yong¹²³⁴⁵,Lin Lili¹²³⁴⁵,Feng Xiaoming¹²³⁴⁵

Affiliation:

1. Key Laboratory of Green Chemistry & Technology

2. Ministry of Education

3. College of Chemistry

4. Sichuan University

5. Chengdu 610064

Abstract

An enantioselective [3 + 2] annulation of donor–acceptor aziridines with aldehydes utilizing a relay catalyst system of Nd(OTf)₃/N,N′-dioxide/LiNTf₂ has been realized.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04151A

Reference54 articles.

1. Ring Expansions of Vinyloxiranes, -thiiranes, and -aziridines: Synthetic Approaches, Challenges, and Catalytic Success Stories

2. Synthesis and Applications of Vinylaziridines and Ethynylaziridines

3. Synthesis and Reactivity of 2-(Carboxymethyl)aziridine Derivatives

4. Phosphine-Promoted [3 + 3] Annulations of Aziridines With Allenoates: Facile Entry Into Highly Functionalized Tetrahydropyridines

5. Cyclocarboamination of Alkynes with Aziridines: Synthesis of 2,3-Dihydropyrroles by a Catalyzed Formal [3 + 2] Cycloaddition

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