Dehydrocoupling of phosphine–boranes using the [RhCp*Me(PMe3)(CH2Cl2)][BArF4] precatalyst: stoichiometric and catalytic studies-Reference-Cited by-同舟云学术

Dehydrocoupling of phosphine–boranes using the [RhCp*Me(PMe3)(CH2Cl2)][BArF4] precatalyst: stoichiometric and catalytic studies

Published:2016 Issue:3 Volume:7 Page:2414-2426
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hooper Thomas N.¹²³⁴⁵,Weller Andrew S.¹²³⁴⁵,Beattie Nicholas A.⁶⁷⁸⁵,Macgregor Stuart A.⁶⁷⁸⁵

Affiliation:

1. Department of Chemistry

2. Chemistry Research Laboratories

3. University of Oxford

4. Oxford

5. UK

6. Institute of Chemical Sciences

7. Heriot Watt University

8. Edinburgh

Abstract

Detailed experimental and computational studies are reported on the fundamental B–H and P–H bond activation steps involved in the dehydrocoupling/dehydropolymerization of primary and secondary phosphine–boranes, H₃B·PPhR′H (R = Ph, H), using the [RhCp*(PMe₃)Me(ClCH₂Cl)][BAr^F₄] catalyst.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC04150C

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