Thermal behaviors during lithium diffusion in Li<sub>0.4</sub>WO<sub>3</sub> bronze studied by elastic and quasi-elastic neutron scattering-Reference-Cited by-同舟云学术

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Thermal behaviors during lithium diffusion in Li_0.4WO₃ bronze studied by elastic and quasi-elastic neutron scattering

Published:2024 Issue:22 Volume:26 Page:16191-16199
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Murshed M. Mangir¹²^ORCID,Fischer Michael³²^ORCID,Koza Michael M.⁴^ORCID,Gesing Th. M.¹²^ORCID

Affiliation:

1. Univeristy of Bremen, Institute of Inorganic Chemistry and Crystallography, Leobener Straße 7, D-28359 Bremen, Germany

2. Univeristy of Bremen, MAPEX Center for Materials and Processes, Bibliothekstraße 1, D-28359 Bremen, Germany

3. University of Bremen, Crystallography, Faculty of Geosciences, Klagenfurter Straße 2-4, D-28359 Bremen, Germany

4. Institut Laue Langevin, 38042 GRENOBLE Cedex 9, France

Abstract

Crystal structure of Li0.4WO3 bronze, showing 2a and 6b Wyckoff sites and LiOx coordination. Upon heating, Li+ moves from preferential 6b to 2a site, leading to thermal expansion anomaly due to interactions with the framework followed by WO6 tilting.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00752B

Reference31 articles.

1. The Lithium Tungsten Bronzes1

2. Electrochromic tungsten oxide films: Review of progress 1993–1998

3. WO3-based electrochromic windows - problems and status

4. Electrochromic Devices Based on Porous Tungsten Oxide Thin Films

5. Lithium intercalation intoWO3and the phase diagram ofLixWO3

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