Reaction of imidazoline-2-selone derivatives with mesityltellurenyl iodide: a unique example of a 3c-4e Se→Te←Se three-body system embedding a tellurenyl cation-Reference-Cited by-同舟云学术

Reaction of imidazoline-2-selone derivatives with mesityltellurenyl iodide: a unique example of a 3c-4e Se→Te←Se three-body system embedding a tellurenyl cation

Published:2019 Issue:30 Volume:43 Page:11821-11831
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Aragoni M. Carla¹²³⁴,Arca Massimiliano¹²³⁴^ORCID,Blake Alexander J.⁵⁶⁷⁸^ORCID,Cadoni Enzo¹²³⁴,Copolovici Lucian O.⁹¹⁰¹¹¹²¹³,Isaia Francesco¹²³⁴^ORCID,Lippolis Vito¹²³⁴^ORCID,Murgia Sergio¹²³⁴^ORCID,Pop Alexandra M.¹⁴¹⁵¹⁶¹⁷¹⁸,Silvestru Cristian¹⁴¹⁵¹⁶¹⁷¹⁸^ORCID,Tidey Jeremiah P.⁵⁶⁷⁸,Varga Richard A.¹⁴¹⁵¹⁶¹⁷¹⁸^ORCID

Affiliation:

1. Dipartimento di Scienze Chimiche e Geologiche

2. Università degli Studi di Cagliari

3. 09042 Monserrato (Cagliari)

4. Italy

5. School of Chemistry

6. University of Nottingham

7. Nottingham NG7 2RD

8. UK

9. Faculty of Food Engineering

10. Tourism and Environmental Protection, and Institute of Technical and Natural Sciences Research-Development-Innovation

11. “Aurel Vlaicu” University

12. Arad

13. Romania

14. Department of Chemistry

15. Supramolecular Organic and Organometallic Chemistry Centre (SOOMCC)

16. Faculty of Chemistry and Chemical Engineering

17. Babeş-Bolyai University

18. 400028 Cluj-Napoca

Abstract

1,2-Bis(3-methyl-4-imidazolin-2-selone)ethane was used to stabilize the first example of an authentic mesityltellurenyl cation, [MesTe]⁺, as a charge transfer adduct featuring a 3c-4e Se→Te←Se three-body system.

Funder

Regione Autonoma della Sardegna

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ01593K

Reference83 articles.

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