Organocatalytic diastereo- and atropo-selective construction of eight-membered bridged (hetero)biaryls <i>via</i> asymmetric intramolecular [3 + 2] cycloaddition-Reference-Cited by-同舟云学术

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Organocatalytic diastereo- and atropo-selective construction of eight-membered bridged (hetero)biaryls via asymmetric intramolecular [3 + 2] cycloaddition

Published:2024 Issue:23 Volume:15 Page:8880-8887
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Yue¹,Huang Yue¹,Bao Xiaoze²^ORCID,Wei Xingfu¹,Wei Shiqiang¹,Qu Jingping¹^ORCID,Wang Baomin¹^ORCID

Affiliation:

1. Department of Pharmaceutical Engineering, State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P. R. China

2. College of Pharmaceutical Science & Collaborative Innovation Center of Yangtze River Delta Region Green Pharmaceuticals, Zhejiang University of Technology, Hangzhou 310014, P. R. China

Abstract

Axially chiral eight-membered bridged (hetero)biaryls have been constructed via organocatalytic intramolecular [3 + 2] cycloaddition of innovative (hetero)biaryl aldehydes with 3-amino oxindole hydrochlorides.

Funder

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC01892C

Reference67 articles.

1. Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

2. Stereoselective Total Synthesis of Axially Chiral Natural Products via Biaryl Lactones

3. Modified BINOL Ligands in Asymmetric Catalysis

4. Non-Symmetrically Substituted 1,1‘-Binaphthyls in Enantioselective Catalysis

5. Assessing Atropisomer Axial Chirality in Drug Discovery and Development

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