Hydrogenation of an iridium-coordinated imidazol-2-ylidene ligand fragment

Author:

Hernández-Juárez M.12345ORCID,López-Serrano J.12345ORCID,González-Herrero P.26789ORCID,Rendón N.12345ORCID,Álvarez E.12345ORCID,Paneque M.12345ORCID,Suárez A.12345ORCID

Affiliation:

1. Instituto de Investigaciones Químicas (IIQ)

2. Departamento de Química Inorgánica

3. Centro de Innovación en Química Avanzada (ORFEO-CINQA)

4. CSIC

5. Universidad de Sevilla

6. Facultad de Química

7. Universidad de Murcia

8. Murcia

9. Spain

Abstract

The unprecedented hydrogenation of a metal-coordinated imidazolylidene to imidazolidinylidene is observed under mild conditions in an iridium complex containing a metalated lutidine derived CNP ligand.

Funder

Consejo Nacional de Ciencia y Tecnología

Ministerio de Economía y Competitividad

Secretaría de Ciencia, Tecnología e Innovación del Distrito Federal

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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