Synthesis of high cis-1,4 polybutadiene with narrow molecular weight distribution via a neodymium-based binary catalyst
Author:
Affiliation:
1. The Key Laboratory of Space Applied Physics and Chemistry
2. Ministry of Education
3. Shaanxi Key Laboratory of Macromolecular Science and Technology
4. School of Science
5. Northwestern Polytechnical University
Abstract
Complex Nd(CF3SO3)3*3TOP with good solubility was synthesized to prepare polybutadiene with high cis-1,4-unit content and narrow molecular weight distribution.
Funder
Ministry of Industry and Information Technology of the People's Republic of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA02656D
Reference33 articles.
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3. Highly cis-1,4 Selective Polymerization of Dienes with Homogeneous Ziegler−Natta Catalysts Based on NCN-Pincer Rare Earth Metal Dichloride Precursors
4. Z. C.Zhang , D. M.Cui , B. L.Wang , B.Liu and Y.Yang , Polymerization of 1,3-Conjugated Dienes with Rare-Earth Metal Precursors , Springer-Verlag , Berlin Heidelberg , 2010
5. Ultra high cis polybutadiene by monomeric neodymium catalyst and its tensile and dynamic properties
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