Tuning ESIPT-coupled luminescence by expanding π-conjugation of a proton acceptor moiety in ESIPT-capable zinc(<scp>ii</scp>) complexes with 1-hydroxy-1<i>H</i>-imidazole-based ligands-Reference-Cited by-同舟云学术

Tuning ESIPT-coupled luminescence by expanding π-conjugation of a proton acceptor moiety in ESIPT-capable zinc(ii) complexes with 1-hydroxy-1H-imidazole-based ligands

Published:2022 Issue:39 Volume:51 Page:15166-15188
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Shekhovtsov Nikita A.¹^ORCID,Nikolaenkova Elena B.²,Berezin Alexey S.¹^ORCID,Plyusnin Victor F.³,Vinogradova Katerina A.¹^ORCID,Naumov Dmitry Yu.¹,Pervukhina Natalia V.¹,Tikhonov Alexsei Ya.²,Bushuev Mark B.¹^ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3, Acad. Lavrentiev Ave., Novosibirsk, 630090, Russia

2. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9, Acad. Lavrentiev Ave., Novosibirsk, 630090, Russia

3. Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 3, Institutskaya str., Novosibirsk, 630090, Russia

Abstract

Tuning ESIPT by expanding π-conjugation of a proton-accepting moiety: the quinolin-2-yl group facilitates the delocalization of electrical charge and promotes the ESIPT reaction.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02460H

Reference187 articles.

1. Proton-transfer reaction dynamics

2. Excited-state proton transfer reactions I. Fundamentals and intermolecular reactions

3. Excited-state proton transfer reactions II. Intramolecular reactions