NO˙ disproportionation by a {RhNO}9 pincer-type complex-Reference-Cited by-同舟云学术

NO˙ disproportionation by a {RhNO}9 pincer-type complex

Published:2017 Issue:48 Volume:46 Page:16878-16884
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gaviglio Carina¹²³⁴⁵^ORCID,Pellegrino Juan⁶⁷⁸⁹¹⁰^ORCID,Milstein David¹¹¹²¹³¹⁴^ORCID,Doctorovich Fabio⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. Comisión Nacional de Energía Atómica

2. CAC-GIyANN

3. Departamento de Física de la Materia Condensada

4. Buenos Aires

5. Argentina

6. Departamento de Química Inorgánica

7. Analítica

8. y Química Física

9. Facultad de Ciencias Exactas y Naturales

10. Universidad de Buenos Aires. INQUIMAE-CONICET

11. Department of Organic Chemistry

12. The Weizmann Institute of Science

13. Rehovot

14. Israel

Abstract

NO˙ disproportionation by the pincer-type complex [Rh(PCP^tBu)(NO)]˙ (1˙) results in the formation of Rh(PCP^tBu)(NO)(NO₂) (2) with coordinated nitrite and quantitative release of N₂O.

Funder

Agencia Nacional de Promoción Científica y Tecnológica

Universidad de Buenos Aires

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03944A

Reference31 articles.

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4. Structures of Metal Nitrosyls

5. Principles of structure, bonding, and reactivity for metal nitrosyl complexes

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