Controllable double CF2-insertion into sp2 C–Cu bond using TMSCF3: a facile access to tetrafluoroethylene-bridged structures
Author:
Affiliation:
1. Key Laboratory of Organofluorine Chemistry
2. Center for Excellence in Molecular Synthesis
3. Shanghai Institute of Organic Chemistry
4. University of Chinese Academy of Sciences
5. Chinese Academy of Sciences
Abstract
Copper-mediated controllable double CF2 insertion into sp2 C–Cu bond and subsequent cross-coupling reaction open the door to the synthesis of an array of valuable tetrafluoroethylene-bridged molecules.
Funder
National Basic Research Program of China
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/C9SC05018C
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3. I. Ojima , Fluorine in Medicinal Chemistry and Chemical Biology , Wiley-Blackwell , Chichester, U.K. , 2009
4. Organic fluorine compounds: a great opportunity for enhanced materials properties
5. Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species
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