Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst-Reference-Cited by-同舟云学术

Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst

Published:2015 Issue:1 Volume:5 Page:320-324
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Postigo Lorena¹²³,Ventura Maria⁴⁵⁶⁷⁸,Cuenca Tomás⁴⁵⁶⁷⁸,Jiménez Gerardo⁴⁵⁶⁷⁸,Royo Beatriz¹²³

Affiliation:

1. Instituto de Tecnología Química e Biológica da Universidade Nova de Lisboa. Av. da República

2. EAN

3. Portugal

4. Departamento de Química Orgánica y Química Inorgánica

5. Universidad de Alcalá

6. Campus Universitario

7. 28871 Alcalá de Henares

8. Spain

Abstract

A cyclopentadienyl–silsesquioxane titanium complex efficiently catalyses the selective oxidation of sulfides to sulfoxides (85–98% yield in 5 min at ambient temperature) and sulfones with near-stochiometric amount of aqueous H₂O₂ in methanol.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CY/C4CY00965G

Reference55 articles.

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2. Recent Developments in the Synthesis and Utilization of Chiral Sulfoxides

3. Oxidation of sulfides to sulfoxides. Part 1: Oxidation using halogen derivatives

4. Enantioselective Synthesis of Sulfoxides: 2000−2009

5. Science and technology of novel processes for deep desulfurization of oil refinery streams: a review⋆

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