Modeling TADF in organic emitters requires a careful consideration of the environment and going beyond the Franck–Condon approximation
Author:
Affiliation:
1. Jan-Michael Mewes
2. Centre For Theoretical Chemistry and Physics
3. New-Zealand Institute for Advanced Study
4. Massey University (Albany)
5. 0632 Auckland
Abstract
Twisted: Efficient thermally-activated delayed fluorescence (TADF) of organic emitters emerges from a delicate interplay of nuclear relaxation, dielectric stabilization and post Franck–Condon effects along the donor–acceptor twisting coordinate.
Funder
Alexander von Humboldt-Stiftung
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP01792A
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