Influence of the substituents of the thiol ligand on the optical properties of AuCu<sub>14</sub>-Reference-Cited by-同舟云学术

Influence of the substituents of the thiol ligand on the optical properties of AuCu₁₄

Published:2024 Issue:57 Volume:60 Page:7374-7377
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhao Yu-Jing¹,Yang Jin-Sen¹²,Li Jing³,Si Yu-Bing¹,Xiao Lu-Yao¹,Wang Zhao-Yang¹^ORCID,Hu Jia-Hua¹,Dong Xi-Yan¹²^ORCID,Zang Shuang-Quan¹^ORCID

Affiliation:

1. Laboratory of Crystalline Molecular Functional Materials, Green Catalysis Center and College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

2. College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454000, China

3. School of Science, Xuchang University, 461000, Xuchang, China

Abstract

Relative to the AuCu14 cluster with an –F group, AuCu14 with a –C(CH3)3 group showed higher photoluminescence quantum yield (PLQY) and slower internal conversion (IC) and intersystem crossing (ISC) rate.

Funder

National Natural Science Foundation of China

Science and Technology Innovation Talents in Universities of Henan Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC01747A

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