Efficient photogeneration of nonacene on nanostructured graphene

Author:

Ayani Cosme G.12,Pisarra Michele23ORCID,Urgel José I.24ORCID,Navarro Juan Jesús12,Díaz Cristina35ORCID,Hayashi Hironobu6ORCID,Yamada Hiroko6ORCID,Calleja Fabian2,Miranda Rodolfo125,Fasel Roman47ORCID,Martín Fernando135ORCID,Vázquez de Parga Amadeo L.125ORCID

Affiliation:

1. Dep Física de la Materia Condensada, Universidad Autónoma de Madrid, Cantoblanco 28049, Madrid, Spain

2. IMDEA-Nanociencia, Calle Faraday 9, Cantoblanco 28049, Madrid, Spain

3. Dep. Química Módulo 13, Universidad Autónoma de Madrid, Cantoblanco, 28049 Madrid, Spain

4. Empa, Swiss Federal Laboratories for Material Science and Technology, 8600 Dübendorf, Switzerland

5. Condensed Matter Physics Center (IFIMAC), Cantoblanco, 28049 Madrid, Spain

6. Graduate School of Science and Technology, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama-cho, Ikoma 630-0192, Japan

7. Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, 3012 Bern, Switzerland

Abstract

The presence of an unoccupied surface state resonantly coupled to the π* affinity levels of the precursors, spatially localized in the regions where the precursors are adsorbed, produces 100% yield in the photogeneration of nonacenes.

Funder

Consejería de Educación, Juventud y Deporte, Comunidad de Madrid

Secretaría de Estado de Investigación, Desarrollo e Innovación

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Core Research for Evolutional Science and Technology

Ministerio de Ciencia, Innovación y Universidades

Ministerio de Economía y Competitividad

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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