Transition-metal-like bonding behaviors of a boron atom in a boron-cluster boronyl complex [(η7-B7)-B-BO]−-Reference-Cited by-同舟云学术

Transition-metal-like bonding behaviors of a boron atom in a boron-cluster boronyl complex [(η7-B7)-B-BO]−

Published:2021 Issue:23 Volume:12 Page:8157-8164
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Tian Wen-Juan¹²³⁴⁵^ORCID,Chen Wei-Jia⁶⁷⁸⁹,Yan Miao¹²³⁴⁵,Li Rui¹²³⁴⁵,Wei Zhi-Hong¹²³⁴⁵,Chen Teng-Teng⁶⁷⁸⁹,Chen Qiang¹²³⁴⁵,Zhai Hua-Jin¹²³⁴⁵^ORCID,Li Si-Dian¹²³⁴⁵^ORCID,Wang Lai-Sheng⁶⁷⁸⁹^ORCID

Affiliation:

1. Nanocluster Laboratory

2. Institute of Molecular Science

3. Shanxi University

4. Taiyuan 030006

5. China

6. Department of Chemistry

7. Brown University

8. Providence

9. USA

Abstract

The global minimum of the B₉O⁻ cluster is found to have an umbrella-like structure, where the central B atom exhibits transition-metal-like bonding properties, coordinated by a η⁷-B₇ ligand on one side and a BO ligand on the other.

Funder

National Science Foundation

National Natural Science Foundation of China

Shanxi University

Natural Science Foundation of Shanxi Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC00534K

Reference72 articles.