Investigation of the “bent sandwich-like” divalent lanthanide hydro-tris(pyrazolyl)borates Ln(TpiPr2)2 (Ln = Sm, Eu, Tm, Yb)-Reference-Cited by-同舟云学术

Investigation of the “bent sandwich-like” divalent lanthanide hydro-tris(pyrazolyl)borates Ln(TpiPr2)2 (Ln = Sm, Eu, Tm, Yb)

Published:2015 Issue:10 Volume:39 Page:7617-7625
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kühling Marcel¹²³⁴,Wickleder Claudia⁵⁶⁷⁴,Ferguson Michael J.⁸⁹¹⁰¹¹,Hrib Cristian G.¹²³⁴,McDonald Robert⁸⁹¹⁰¹¹,Suta Markus⁵⁶⁷⁴,Hilfert Liane¹²³⁴,Takats Josef⁸⁹¹⁰¹¹,Edelmann Frank T.¹²³⁴

Affiliation:

1. Chemisches Institut der Otto-von-Guericke-Universität Magdeburg

2. Universitätsplatz 2

3. 39106 Magdeburg

4. Germany

5. Universität Siegen

6. Anorganische Chemie

7. 57068 Siegen

8. Department of Chemistry

9. University of Alberta

10. Edmonton

11. Canada T6G 2G2

Abstract

Synthesis, luminescence and reactivity of the lanthanide(ii) “bent sandwich-like” hydro-tris(pyrazolyl)borate complexes Ln(Tp^iPr2)₂ (Ln = Sm, Eu, Tm, Yb) have been investigated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/NJ/C5NJ00568J

Reference59 articles.

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2. Synthesis and crystallographic characterization of an unsolvated, monomeric samarium bis(pentamethylcyclopentadienyl) organolanthanide complex, (C5Me5)2Sm

3. Solution synthesis and crystallographic characterization of the divalent organosamarium complexes (C5Me5)2Sm(THF)2 and [(C5Me5)Sm(.mu.-I)(THF)2]2

4. Synthesis and x-ray crystal structure of bis(pentamethylcyclopentadienyl) complexes of samarium and europium: (C5Me5)2Sm and (C5Me5)2Eu

5. The complex (Me5C5)2Yb(.mu.-Me)Be(C5Me5): a model for methane coordination?

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