O–H stretching frequency red shifts do not correlate with the dissociation energies in the dimethylether and dimethylsulfide complexes of phenol derivatives
Author:
Affiliation:
1. Department of Chemical Sciences
2. Tata Institute of Fundamental Research
3. Mumbai 400 005
4. India
Abstract
In the complexes of dimethylether and dimethylsulfide with various phenol derivatives the conventional Badger–Bauer rule is violated, i.e., the red shift in the OH stretching frequency does not correlate with the H-bonding strength.
Funder
Department of Atomic Energy, Government of India
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP01589J
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