Giant zirconium-bisphosphonate nano-ribbons and their liquid crystalline phase behaviour in water

Author:

Schmelter Dirk123,Tagné Rodolphe Nekui123,Cortes-Sanchez Hector45631,Schmedt auf der Günne Jörn4563ORCID,Welter Edmund7893,Hintze-Bruening Horst10111231ORCID

Affiliation:

1. BASF Coatings Division

2. 48165 Münster

3. Germany

4. Inorganic Materials Chemistry

5. University of Siegen

6. 57076 Siegen

7. Deutsches Elektronen Synchrotron

8. A Research Centre of the Helmholtz Association

9. 22607 Hamburg

10. Paderborn University

11. Department of Chemistry

12. 33098 Paderborn

Abstract

Several micrometer long nano-ribbons of sodium etidronate linked Zr4O24 clusters are formed in decimolar concentration. Extraction of Na+ leads to stripping into filaments which adopt a hexagonal order and persist after neutralization with ammonia.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference37 articles.

1. A. Clearfield and K.Demadis , Metal Phosphonate Chemistry: From Synthesis to Applications , Royal Society of Chemistry , 1st edn, 2012 , pp. 279–316

2. Synthesis of Mesoporous Zirconium Organophosphonate Solid‐Acid Catalysts

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