[4 + 2]-Cycloadditions of a thiazol-based tricyclic 1,4-diphosphinine and a new easy 1,4-diphosphinine protection deprotection strategy-Reference-Cited by-同舟云学术

[4 + 2]-Cycloadditions of a thiazol-based tricyclic 1,4-diphosphinine and a new easy 1,4-diphosphinine protection deprotection strategy

Published:2020 Issue:36 Volume:49 Page:12776-12779
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Begum Imtiaz¹²³,Kalisch Tim¹²³,Schnakenburg Gregor¹²³,Kelemen Zsolt⁴⁵⁶⁷,Nyulászi László⁴⁵⁶⁷^ORCID,Streubel Rainer¹²³^ORCID

Affiliation:

1. Institut für Anorganische Chemie der Rheinischen Friedrich-Wilhelms-Universität Bonn

2. 53121 Bonn

3. Germany

4. Department of Inorganic and Analytical Chemistry and MTA-BME Computation Driven Chemistry Research Group

5. Budapest University of Technology and Economics

6. 1111 Budapest

7. Hungary

Abstract

Diels–Alder-reactions of a thiazol-2-thione-based, tricyclic 1,4-diphosphinine were investigated, showing that the central aromatic π-system can react with various dienophiles. In one case, photochemical deprotection of the 1,4-diphosphinine was found.

Funder

Rheinische Friedrich-Wilhelms-Universität Bonn

European Commission

Nemzeti Kutatási Fejlesztési és Innovációs Hivatal

Alexander von Humboldt-Stiftung

Deutscher Akademischer Austauschdienst

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02529A