Distorted copper(ii) radicals with sterically hindered salens: electronic structure and aerobic oxidation of alcohols-Reference-Cited by-同舟云学术

Distorted copper(ii) radicals with sterically hindered salens: electronic structure and aerobic oxidation of alcohols

Published:2020 Issue:37 Volume:49 Page:12990-13002
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kunert R.¹²³⁴⁵,Philouze C.¹²³⁴⁵,Berthiol F.¹²³⁴⁵,Jarjayes O.¹²³⁴⁵^ORCID,Storr T.⁶⁷⁸⁹^ORCID,Thomas F.¹²³⁴⁵^ORCID

Affiliation:

1. Univ. Grenoble Alpes

2. CNRS

3. DCM

4. 38000 Grenoble

5. France

6. Department of Chemistry

7. Simon Fraser University

8. Burnaby

9. Canada

Abstract

Strongly distorted copper salen complexes show a unique stability in four different redox states by CV. Copper phenoxyl radical complexes are structurally characterized. They promote the catalytic aerobic oxidation of 2-phenylethanol under air.

Funder

Agence Nationale de la Recherche

Mitacs

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02524K

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