CFA-13 – a bifunctional perfluorinated metal–organic framework featuring active Cu(i) and Cu(ii) sites
Author:
Affiliation:
1. Augsburg University
2. Institute of Physics
3. Chair of Solid State and Materials Chemistry
4. 86159 Augsburg
5. Germany
Abstract
(Me2NH2)[CFA-13] is a perfluorinated metal–organic framework containing both trinuclear [CuI3(pz)4]− and Cu(ii) paddle-wheel secondary building units.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02512B
Reference43 articles.
1. Supramolecular Isomerism, Framework Flexibility, Unsaturated Metal Center, and Porous Property of Ag(I)/Cu(I) 3,3‘,5,5‘-Tetrametyl-4,4‘-Bipyrazolate
2. CFA-2 and CFA-3 (Coordination Framework Augsburg University-2 and -3); novel MOFs assembled from trinuclear Cu(i)/Ag(i) secondary building units and 3,3′,5,5′-tetraphenyl-bipyrazolate ligands
3. A luminescent cationic metal–organic framework featuring [Cu–pyrazolate]3 units for volatile organic compound sensing
4. Remote Stabilization of Copper Paddlewheel Based Molecular Building Blocks in Metal–Organic Frameworks
5. A Copper-Based Metal-Organic Framework as an Efficient and Reusable Heterogeneous Catalyst for Ullmann and Goldberg Type C–N Coupling Reactions
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