Proton affinity and gas phase basicity of diamandoid molecules: diamantane to C<sub>131</sub>H<sub>116</sub>-Reference-Cited by-同舟云学术

Proton affinity and gas phase basicity of diamandoid molecules: diamantane to C₁₃₁H₁₁₆

Published:2022 Issue:5 Volume:24 Page:3470-3477
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Camacho-Mojica Dulce C.¹^ORCID,Ha Jong-Kwon²,Min Seung Kyu¹²^ORCID,Vianello Robert³^ORCID,Ruoff Rodney S.¹²⁴⁵^ORCID

Affiliation:

1. Center for Multidimensional Carbon Materials (CMCM), Institute for Basic Science (IBS), Ulsan 44919, Republic of Korea

2. Department of Chemistry, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea

3. Laboratory for the Computational Design and Synthesis of Functional Materials, Division of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, 10 000 Zagreb, Croatia

4. Department Materials Science and Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea

5. School of Chemical Engineering and Energy Science, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea

Abstract

Proton affinities and gas phase basicities are computed for diamantane (C14H20), triamantane (C18H24), ‘globular and planar’ isomers of tetramantane (C22H28) and pentamantane (C26H32), and for one ‘globular’ isomer of each of the larger diamondoids: C51H58, C78H72, C102H90, and C131H116.

Funder

Institute for Basic Science

National Research Foundation

Hrvatska Zaklada za Znanost

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP04177K

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1. Stable Carbonium Ions. LIV. Protonation of and Hydride Ion Abstraction from Cycloalkanes and Polycycloalkanes in Fluorosulfonic Acid-Antimony Pentafluoride