Alkoxide-catalyzed addition of alkyl carbonates across alkynes – stereoselective synthesis of (E)-β-alkoxyacrylates
Author:
Affiliation:
1. Fakultät für Chemie und Biochemie
2. Ruhr Universität Bochum
3. 44801 Bochum
4. Germany
Abstract
Terminal alkynes were converted to (E)-β-alkoxyacrylates via regio- and stereoselective addition of dialky carbonates catalyzed by potassium methoxide.
Funder
Deutsche Bundesstiftung Umwelt
Publisher
Royal Society of Chemistry (RSC)
Subject
Pollution,Environmental Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/GC/C6GC03168D
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3. Vinylic carbanions in synthesis. Novel syntheses of iso-gregatin B, iso-aspertetronin A and related O-methyl tetronic acids
4. Inhibition of NF-Kappa B Activation by Penicillic Acid and Dihydropenicillic Acid Isolated from Fungi
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