Chiral six-coordinate Dy(iii) and Tb(iii) complexes of an achiral ligand: structure, fluorescence, and magnetism-Reference-Cited by-同舟云学术

Chiral six-coordinate Dy(iii) and Tb(iii) complexes of an achiral ligand: structure, fluorescence, and magnetism

Published:2017 Issue:38 Volume:46 Page:13035-13042
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Liu Mei-Jiao¹²³⁴,Yuan Juan¹²³⁴,Zhang Yi-Quan⁵⁶⁷⁸⁴^ORCID,Sun Hao-Ling⁹¹⁰¹⁰¹¹⁴^ORCID,Liu Cai-Ming¹²¹³¹⁴¹⁵¹⁶^ORCID,Kou Hui-Zhong¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Tsinghua University

3. Beijing 100084

4. P. R. China

5. Jiangsu Key Laboratory for NSLSCS

6. School of Physical Science and Technology

7. Nanjing Normal University

8. Nanjing 210023

9. Department of Chemistry and Beijing Key Laboratory of Energy Conversion and Storage Materials

10. Beijing Normal University

11. Beijing 100875

12. Beijing National Laboratory for Molecular Sciences

13. Center for Molecular Science

14. Institute of Chemistry

15. Chinese Academy of Sciences

16. Beijing 100190

Abstract

Two new chiral six-coordinate lanthanide complexes are obtained using an achiral ligand. Complex [Zn₃Dy] displays field-induced slow magnetization relaxation, while complex [Zn₃Tb] exhibits intense green photofluorescence and triboluminescence.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02409F

Reference71 articles.

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