Csp–Csp bond cleavage and fragment coupling: a transition metal-free “extrusion and recombination” approach towards synthesis of 1,2-diketones-Reference-Cited by-同舟云学术

Csp–Csp bond cleavage and fragment coupling: a transition metal-free “extrusion and recombination” approach towards synthesis of 1,2-diketones

Published:2021 Issue:19 Volume:8 Page:5389-5396
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Gujjarappa Raghuram¹^ORCID,Vodnala Nagaraju¹²,Kandpal Ashish³^ORCID,Roy Lisa³^ORCID,Gupta Sreya⁴,Malakar Chandi C.¹^ORCID

Affiliation:

1. Department of Chemistry, National Institute of Technology Manipur, Langol, Imphal 795004, Manipur, India

2. Department of Chemistry, Multi-storey building, HauzKhas, Indian Institute of Technology Delhi, New Delhi, 110016, India

3. Institute of Chemical Technology Mumbai – IOC Odisha Campus Bhubaneswar, IIT Kharagpur Extension Centre, Bhubaneswar 751013, India

4. Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research (NIPER), Kolkata, Chunilal Bhawan, 168, Maniktala Main Road, Kolkata 700054, India

Abstract

A metal-free strategy for C–C bond activation of 1,3-diynes has been established via an “extrusion and recombination” approach to derive structurally important 1,2-diketones in good yields with excellent selectivity.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO00848J

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