Ion-pairing π-electronic systems: ordered arrangement and noncovalent interactions of negatively charged porphyrins

Author:

Sasano Yoshifumi12345,Tanaka Hiroki12345,Haketa Yohei12345ORCID,Kobayashi Yoichi12345ORCID,Ishibashi Yukihide67895ORCID,Morimoto Tatsuki11011125ORCID,Sato Ryuma13145ORCID,Shigeta Yasuteru151617518ORCID,Yasuda Nobuhiro1920215ORCID,Asahi Tsuyoshi67895ORCID,Maeda Hiromitsu12345ORCID

Affiliation:

1. Department of Applied Chemistry

2. College of Life Sciences

3. Ritsumeikan University

4. Kusatsu 525-8577

5. Japan

6. Department of Materials Science and Biotechnology

7. Graduate School of Science and Engineering

8. Ehime University

9. Matsuyama 790-8577

10. School of Engineering

11. Tokyo University of Technology

12. Hachioji 192-0982

13. RIKEN Center for Biosystems Dynamics Research (BDR)

14. Suita 565-0874

15. Center for Computational Sciences

16. University of Tsukuba

17. Tsukuba 305-8577

18. Department of Physics

19. Diffraction and Scattering Division

20. Japan Synchrotron Radiation Research Institute

21. Sayo 679-5198

Abstract

π-Electronic ion pairs comprising porphyrin-based π-electronic anions have exhibited characteristic assembling modes and resulting electronic properties such as solid-state absorption and photoinduced electron transfer.

Funder

Japan Society for the Promotion of Science

Ritsumeikan Global Innovation Research Organization, Ritsumeikan University

RIKEN

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference70 articles.

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2. P. J. Cragg , Supramolecular Chemistry, From Biological Inspiration to Biomedical Applications , Springer , 2010

3. Supramolecular Chemistry: From Molecules to Nanomaterials , ed. P. A. Gale and J. W. Steed , Wiley , 2012

4. Interactions with Aromatic Rings in Chemical and Biological Recognition

5. On the Importance and Origin of Aromatic Interactions in Chemistry and Biodisciplines

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