Palladium-catalyzed decarboxylative [2 + 3] cyclocarbonylation reactions of [60]fullerene: selective synthesis of [60]fullerene-fused 3-vinylcyclopentan-4-ones and cyclopentane-4-carbaldehydes-Reference-Cited by-同舟云学术

Palladium-catalyzed decarboxylative [2 + 3] cyclocarbonylation reactions of [60]fullerene: selective synthesis of [60]fullerene-fused 3-vinylcyclopentan-4-ones and cyclopentane-4-carbaldehydes

Published:2022 Issue:20 Volume:9 Page:5564-5570
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Liu Tong-Xin¹²^ORCID,Zhang Chuanjie¹,Zhang Pengling¹,Wang Xin¹,Ma Jinliang¹,Zhang Guisheng¹

Affiliation:

1. Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, P. R. China

2. Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China

Abstract

A new palladium-catalyzed decarboxylative strategy has been developed toward direct cyclocarbonylation of [60]fullerene, selectively furnishing novel [60]fullerene-fused 3-vinylcyclopentan-4-ones and cyclopentane-4-carbaldehydes.

Funder

National Natural Science Foundation of China

Higher Education Discipline Innovation Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO01116F

Reference78 articles.

1. Fullerene for organic electronics

2. N.Martín and F.Giacalone , Fullerene Polymers: Synthesis, Properties and Applications , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim, Germany , 2009