Iridium-catalyzed direct C–H arylation of cyclic N-sulfonyl ketimines with arylsiloxanes at ambient temperature
Author:
Affiliation:
1. Organic & Medicinal Chemistry Division
2. CSIR-Indian Institute of Chemical Biology
3. Kolkata 700032
4. India
5. Academy of Scientific and Innovative Research (AcSIR)
Abstract
A highly efficient iridium-catalyzed ortho-selective C–H arylation of weakly coordinating cyclic N-sulfonyl ketimines has been achieved with environmentally benign aryl siloxanes at ambient temperature giving access to a novel class of biaryls.
Funder
Council of Scientific and Industrial Research, India
University Grants Commission
Bristol-Myers Squibb
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB01212B
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4. Palladium-catalyzed cross-coupling reaction of organometalloids through activation with fluoride ion
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