Degradation mechanisms in mixed-cation and mixed-halide CsxFA1−xPb(BryI1−y)3 perovskite films under ambient conditions

Author:

Marchezi Paulo Ernesto1234ORCID,Therézio Eralci Moreira12345,Szostak Rodrigo12346ORCID,Loureiro Hugo Campos1234ORCID,Bruening Karsten789,Gold-Parker Aryeh789ORCID,Melo Maurício A.1011124,Tassone Christopher J.789,Tolentino Helio C. N.61334ORCID,Toney Michael F.789ORCID,Nogueira Ana Flávia1234ORCID

Affiliation:

1. Chemistry Institute

2. University of Campinas

3. Campinas

4. Brazil

5. Physics Institute

6. Brazilian Synchrotron Light Laboratory (LNLS)

7. Stanford Synchrotron Radiation LightSource (SSRL)

8. Menlo Park

9. USA

10. São Carlos Institute of Physics

11. University of São Paulo

12. São Carlos

13. Brazilian Center for Research in Energy and Materials (CNPEM)

Abstract

With in situ ESEM and GIWAXS we saw that the perovskite degradation passes through hexagonal polytypes and is dependent on the composition.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Fundação de Amparo à Pesquisa do Estado de São Paulo

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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