Spin–orbit effects in square-planar Pt(ii) complexes with bidentate and terdentate ligands: theoretical absorption/emission spectroscopy
Author:
Affiliation:
1. Laboratoire de Chimie Quantique UMR-7177 CNRS-UdS
2. Université de Strasbourg
3. F-67008 Strasbourg, France
Abstract
Theoretical “spin-free” (in black) and “spin–orbit” (in red) absorption spectra of [Pt(tpy)Cl]+ and electronic densities characterizing the main intense bands MLCT/XLCT at 384 nm, and MLCT/LC at 326 nm and 250 nm (the experimental spectrum is shown in the inset).
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01822B
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