Polymerization kinetics of bicyclic olefins and mechanism with symmetrical ansa-metallocene catalysts associated with active center count: relationship between their activities and structure and activation path-Reference-Cited by-同舟云学术

Polymerization kinetics of bicyclic olefins and mechanism with symmetrical ansa-metallocene catalysts associated with active center count: relationship between their activities and structure and activation path

Published:2022 Issue:24 Volume:12 Page:15284-15295
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Ali Amjad¹²^ORCID,Naveed Ahmad¹,Shehzad Khurram³⁴⁵^ORCID,Aziz Tariq⁶^ORCID,Rasheed Tahir⁷,Moradian Jamile Mohammadi⁸,Hassan Mobashar¹,Rahman Abdul³⁹,Zhiqiang Fan²^ORCID,Guo Li¹^ORCID

Affiliation:

1. Research School of Polymeric Materials, School of Materials Science & Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China

2. MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, P. R. China

3. School of Micro-Nano Electronics, Hangzhou Global Scientific and Technological Innovation Center (HIC), Zhejiang University, Xiaoshan 311200, China

4. State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, China

5. ZJU-UIUC Joint Institute, Zhejiang University, Jiaxing 314400, China

6. Westlake University, School of Engineering Yunqi Campus, Hangzhou, Zhejiang 310024, PR China

7. Interdisciplinary Research Center for Advanced Materials, King Fahd University of Petroleum and Minerals (KFUPM), Dhahran 31261, Saudi Arabia

8. Biofuels Institute, School of Envinoment, Jiangsu University, Zhenjiang, 212013, P. R. China

9. Stoddart Institute of Molecular Science, Department of Chemistry, Zhejiang University, Hangzhou 310027, China

Abstract

Copolymerization of ethylene (E) with 5-vinyl-2-norbornene (VNB) catalyzed by ansa-metallocenes allows the precise control of essential polymeric properties such as comonomer incorporation, molecular weight (Mw), and polydispersity (Đ).

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D2RA01264B

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3. W.Kaminsky and M.Arndt , Metallocenes for polymer catalysis , in Polymer Synthesis/Polymer Catalysis , Springer , 1997 , pp. 143–187