The formation of benzoxacin-3-ones via intramolecular Nicholas reactions and synthesis of 8-membered heliannuols-Reference-Cited by-同舟云学术

The formation of benzoxacin-3-ones via intramolecular Nicholas reactions and synthesis of 8-membered heliannuols

Published:2021 Issue:33 Volume:19 Page:7152-7155
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

St. Onge Brent¹^ORCID,Green James R.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON, NB 3P4, Canada

Abstract

Intramolecular Nicholas reactions have been shown to give dehydrobenzoxacin-3-one-Co2(CO)6 complexes. This allows the synthesis of (±)-heliannuol K methyl ether and the formal syntheses of (±)-heliannuol K, (±)-heliannuol A, and (−)-heliannuol L.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB01395E

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