Entangled chain polymer liquids under continuous shear deformation: consequences of a microscopically anharmonic confining tube
Author:
Affiliation:
1. Departments of Materials Science
2. University of Illinois
3. Urbana
4. USA
5. Chemistry
Abstract
Deformation-induced changes of tube confinement field significantly modifies the shear rheological response of entangled flexible polymer liquids at WiR < 1.
Funder
U.S. Department of Energy
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SM/C8SM01182F
Reference50 articles.
1. M. Doi and S. F.Edwards , The Theory of Polymer Dynamics , Clarendon Press , Oxford , 1986
2. Reptation of a Polymer Chain in the Presence of Fixed Obstacles
3. Tube theory of entangled polymer dynamics
4. S.-Q. Wang , Nonlinear Polymer Rheology: Macroscopic Phenomenology and Molecular Foundation , Wiley , Hoboken, NJ , 2018
5. A Molecular Theory for Fast Flows of Entangled Polymers
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