Zn/Cu complexes constructed through selective <i>in situ</i> Br–Cl exchange: synthesis, structures, properties, and DFT insights into the Cu-catalyzed mechanism-Reference-Cited by-同舟云学术

Zn/Cu complexes constructed through selective in situ Br–Cl exchange: synthesis, structures, properties, and DFT insights into the Cu-catalyzed mechanism

Published:2022 Issue:16 Volume:24 Page:3026-3034
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Si Chang-Dai¹^ORCID,Zhang Jian-Bin¹,Pan Feng-Feng¹,Wang Peng¹,Liao Tian-Lu¹,Zheng Wan-He¹,Liu Jia-Cheng²,Yuan Kun¹

Affiliation:

1. College of Chemical Engineering and Technology, Tianshui Normal University, Tianshui 741000, People's Republic of China

2. College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of China

Abstract

The coordination polymers of Cu(ii) and Zn(ii) have been synthesized. Simultaneously, the selective in situ Br–Cl exchange mechanism, structures, magnetic properties, and the fluorescence lifetimes of complexes 1–2 are discussed in detail.

Funder

National Natural Science Foundation of China

Tianshui Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CE/D2CE00128D

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5. Tuning of Valence States, Bonding Types, Hierarchical Structures, and Physical Properties in Copper/Halide/Isonicotinate System

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