Cr-dopant induced crystal orientation and shape modulation in Ni2P nanocrystals for improving electrosynthesis of methanol to formate coupled with hydrogen production

Author:

Suryawanshi Umesh P.1,Ghorpade Uma V.2,Yuwono Jodie A.3,Kumar Priyank V.2ORCID,Gaikwad Mayur A.1,Shin Seung Wook4,Jang Jun Sung1ORCID,Jung Hyo Rim1,Suryawanshi Mahesh P.5ORCID,Kim Jin Hyeok1ORCID

Affiliation:

1. Optoelectronics Convergence Research Center and Department of Materials Science and Engineering, Chonnam National University, 300, Yongbong-Dong, Buk-Gu, Gwangju 61186, South Korea

2. School of Chemical Engineering, University of New South Wales, Sydney, NSW, 2052, Australia

3. School of Chemical Engineering, The University of Adelaide, Adelaide, SA, 5005, Australia

4. Rural Research Institute, Korea Rural Community Corporation, 870 Haean-ro Sangnok-gu, Ansan-Si, Gyeonggi-di, 15634, Republic of Korea

5. School of Photovoltaic and Renewable Energy Engineering, University of New South Wales, Sydney, NSW 2052, Australia

Abstract

Cr-doped Ni2P nanorods enable a two-electrode overall methanol splitting (OMeS) system, achieving a lowest voltage of 1.16 V to reach a current density of 10 mA cm−2, compared to the cell voltage of 1.65 V for overall water splitting.

Funder

Australian Research Council

National Research Foundation of Korea

Ministry of Science and ICT, South Korea

Publisher

Royal Society of Chemistry (RSC)

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