Stereoselective alkyne insertion into a bridging hydride at a diiron centre: cis–trans isomerisation and metallacycle formation
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1994/DT/DT9940003389
Reference37 articles.
1. Synthesis and reactivity towards unsaturated organics of the diiron hydride complex [Fe2(CO)4(µ-CO)(µ-H)-(µ-PPh2)(µ-Ph2PCH2PPh2)]
2. The reactivity of bridging hydride ligands at the di-iron centre. Synthesis and reactivity towards alkynes of [Fe2(CO)6(μ-H)(μ-CO)(μ-dppm)][BF4]. X-ray crystal structure of [Fe2(CO)6(μ-PhCCH2)(μ-dppm)][BF4]
3. G. Hogarth and M. H.Lavender, unpublished work.
4. Transition-metal polyhydride complexes
5. Hydrido complexes of the transition metals
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