4 V room-temperature all-solid-state sodium battery enabled by a passivating cathode/hydroborate solid electrolyte interface

Author:

Asakura Ryo12345ORCID,Reber David12345ORCID,Duchêne Léo12345ORCID,Payandeh Seyedhosein12345ORCID,Remhof Arndt12345ORCID,Hagemann Hans6785ORCID,Battaglia Corsin12345ORCID

Affiliation:

1. Materials for Energy Conversion

2. Empa

3. Swiss Federal Laboratories for Materials Science and Technology

4. 8600 Dübendorf

5. Switzerland

6. Département de Chimie-Physique

7. Université de Genève

8. 1211 Geneva 4

Abstract

A self-passivating cathode/electrolyte interface achieves stable, room-temperature long-term cycling of 4 V-class Na3(VOPO4)2F|Na4(CB11H12)2(B12H12)|Na all-solid-state sodium batteries with the highest reported discharge cell voltage and cathode-based specific energy.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Innosuisse - Schweizerische Agentur für Innovationsförderung

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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